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SYS · ONLINEPASS · 63.0%
Open Assay
Independent Testing / Est. 2026
BATCH04·26·B
PASS63.0%
N27
PeptidesCognitiveModafinil

Modafinil

/ Wakefulness-promoting agent (small molecule, sulfinyl class)
TIER 1 · ClinicalN = 0 · TESTING PENDINGMW 273.35 g·mol⁻¹

ALIAS · Provigil (trade) · Alertec (trade — Canada) · Modiodal (trade — France/Japan) · 2-(diphenylmethylsulfinyl)acetamide

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Research use onlyAny dose figures below describe what specific cited studies used, reported factually. Nothing on this page is guidance for human use.READ FIRST →

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§ A · Identity
Primary sequence— sequence not captured —
MW · 273.35CLASS · Wakefulness-promoting agent (small molecule, sulfinyl class)CATEGORY · Cognitive

Tier 1. FDA-approved 1998 for narcolepsy, with subsequent approvals for shift-work sleep disorder (2004) and as adjunct for residual sleepiness in obstructive sleep apnea. Multiple Phase 3 RCTs; DEA Schedule IV controlled substance.

§ B · Mechanism of action

Modafinil is a wakefulness-promoting agent whose precise mechanism remains incompletely characterised. The best-supported molecular action is weak inhibition of the dopamine transporter (DAT), elevating extracellular dopamine in the nucleus accumbens and prefrontal cortex; secondary effects on histaminergic, orexinergic, and noradrenergic systems have also been reported.

Unlike classical stimulants, modafinil does not produce robust monoamine release and shows a more selective wake-promoting profile with reduced peripheral sympathomimetic activity. The compound is structurally distinct from amphetamines and methylphenidate and was originally developed in France in the 1970s as the (R)-enantiomer is the more pharmacologically active form (marketed separately as armodafinil).

§ C · Human clinical evidence

Tier 1. Multiple Phase 3 RCTs supported FDA approval for narcolepsy (1998), shift-work sleep disorder (2004), and OSA-associated residual sleepiness. Off-label investigation in sleep-deprivation cognition (Wesensten 2002) and in shift-work populations (Czeisler 2005 NEJM SHIFT-MOD trial) has generated additional human data on alertness and cognitive performance.

§ D · Primary literature
PubMed11862356Wesensten NJ et al.Maintaining alertness and performance during sleep deprivation: modafinil versus caffeine · Psychopharmacology · human-phase-2Modafinil 100, 200, and 400 mg restored alertness and psychomotor performance during 54.5 hours of sleep deprivation comparable to caffeine 600 mg.Limitations: Healthy military volunteers; acute sleep-deprivation paradigm; not generalisable to chronic dosing.2002
PubMed16079371Czeisler CA et al.Modafinil for excessive sleepiness associated with shift-work sleep disorder · The New England Journal of Medicine · human-phase-3-rctModafinil 200 mg before night shift improved sleep latency on MSLT and reduced Karolinska Sleepiness Scale scores; supported FDA approval for shift-work sleep disorder.Limitations: Modest improvement in functional outcomes; placebo-controlled but residual sleepiness persisted in many participants.2005
§ F · Safety signal

Common adverse events include headache, nausea, anxiety, and insomnia. Rare but serious cutaneous reactions (Stevens-Johnson syndrome, toxic epidermal necrolysis) prompted an FDA warning in 2007. Modafinil is a CYP3A4 inducer and can reduce efficacy of hormonal contraceptives. DEA Schedule IV reflects observed abuse liability lower than amphetamines but non-zero.

§ H · Regulatory status

Regulatory status

FDA status:
FDA-approved
Compounding:
Not eligible for compounding (approved, not in shortage)
§ I · Notable gaps and controversies

The wakefulness mechanism is mechanistically debated — the dopaminergic contribution is well-supported but the broader 'cognitive enhancement in non-sleep-deprived' literature is heterogeneous and confounded by publication bias. Off-label use in healthy adults for cognitive enhancement substantially exceeds approved indications and has limited controlled data on chronic use, dependence, or effects on developing brains.